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This was a 2,400 megawatt coal fired power station, capable of using other fuels.

The power station was alongside Longannet Mine which provided it with coal by conveyor. In addition further coal was delivered by rail.

The rail facility was a large loop from the Stirling, Alloa, Kincardine and Dunfermline Town route. The loop met the main line with triangular junctions allowing a train to approach from either direction or leave in either direction without reversal. Much of the layout was on an area previously used for a rail served MOD depot.

With the closure of the route beyond Kincardine Power Station in 1981 most trains approached from the east, although there was hopper coal loading and later a simple loading pad at Kincardine Power Station from the 1980s.

With the closure of Longannet Mine in 2002 more trains were required and the additional trains, many with imported coal coming from Hunterston High Level Sidings but also from Ravenstruther, Mossend Marshalling Yard, Thornton Marshalling Yard, Inverkeithing Sidings clogged up the railways of the Central Belt and Fife, and battered the Forth Bridge. The Stirling - Alloa - Kincardine line re-opened in 2008.

Failure to win a contract to supply electricity to the National Grid led to closure in 2016. Demolition of the buildings and chimney were in 2021.

Ash from the power station was placed in lagoons. In 1997 the ash was used by Blue Circle at Westbury. Ash was carried in PCA wagons with empties from the power station on their return journey to Killoch Colliery. The PCA wagons were left at Falkland Yard and taken on by the Irvine - Burngallow 'Enterprise' to be dropped off at Newport and finally worked to Westbury.

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